No 4 (2019)

Full Issue

THE PLANT FOR TESTING COATINGS SAMPLES UNDER VARIABLE LOADS

Venediktov A.N., Venediktov N.L.

Abstract

While in operation, the parts with the applied coatings often work under variable loads, which affects the service life of the products. Many papers deal with the study of fatigue properties of such products, however, the study of the influence of variable loads on the structure and properties of the coatings has a fragmented nature. As the determination of fatigue characteristics of samples with the applied coatings is still important, the goal of this paper is to develop the design of the plant for fatigue tests and the technique of testing the samples with coatings under the variable loads. To develop the technique of fatigue tests, the authors created a unique design plant. When developing the plant, the authors considered the fact that the loading of a sample should be regular that the base and the substrate materials will experience stresses constant along the full length of a sample. Using the analytical solution of the strength task, the authors developed the technique of determining the stresses in a coating and a substrate. To prove the appropriateness of using the suggested technique, the numerical methods were used. For this purpose, using the Comsol Multiphysics software in a 2-D setup, the authors were solving the task of determining stresses in a sample consisted of two layers of the materials. In the result of the study, the authors developed the design of an experimental plant for testing samples with coatings with the maximum tensile force of 5000 N and the possibility of smooth change of vibrational frequency. The authors developed and tested the technique of testing samples with coatings without separation of a coating from a substrate. The study showed that the application of the described technique is reasonable if the thickness of a coating is not more than 7 % of the thickness of a substrate.
Frontier Materials & Technologies. 2019;(4):6-12
pages 6-12 views

EFFECT OF IRON CONCENTRATION ON CRYSTALLIZATION OF AN AMORPHOUS ALLOY OF CO-FE-B-NB SYSTEM

Volkov N.A., Abrosimova G.E.

Abstract

In the modern world, technical devices are being constantly improved, creation of which requires materials with the best functional properties. Amorphous and nanocrystalline iron- and cobalt-based alloys are some of such materials. They have proved to be good in the fields of radio- and microelectronics, due to the fact they have high magnetic characteristics. It is also known that these properties can be improved by the formation of a partially crystalline structure is such alloys. However, such a structure cannot always be formed using a standard method of isothermal annealing; therefore, alloying components are added to the alloy composition to slow down the crystallization process. Different content of added components also affects the sequence of phase transformations during crystallization. As most of the properties are structure-dependent, the formed structure also determines the material characteristics. Therefore, establishment of the dependence of the formed structure in amorphous alloys after heat treatment is an important task of condensed matter physics. The crystallization of the amorphous alloys of Co-Fe-B-Nb system was studied by X-ray diffraction. The samples were crystallized using isothermal annealing of the alloys with different content of components under the same conditions. The dependence of the formed structure on the content of an alloying component is determined. It is shown that the formed structure significantly depends on the concentration of iron. With the iron content of 10 at.% and 16 at.%, the structure consists of cubic cobalt nanocrystals and a solid solution of iron in cobalt. With a decrease in the concentration to 5 at.%, the crystallization mechanism changes: crystallization begins with the precipitation of Co23B6 boride crystals. The reasons for the effect of iron concentration in the alloy composition on crystallization are discussed.
Frontier Materials & Technologies. 2019;(4):13-18
pages 13-18 views

THE FORMATION OF THE BANK OF GAITS FOR A CRAWLING SEARCH ROBOT WITH CONTROLLABLE FRICTION IN BEARING SUPPORTS

Vorochaeva L.Y., Savin S.I.

Abstract

The paper considers a three-link crawling snake-like robot, the links of which are connected by two-axis hinges. The robot is equipped with four bearing supports with the controlled coefficient of friction between them and the surface. The device is designed to move inside buildings after the emergencies to search for people under the debris and to transport the essentials to them. The robot is controlled by the operator in two modes: the sequential execution of commands (forward, backward, turn, etc.) and moving from the starting point to the final one. Working in each of the control modes requires the use of the gaits bank. The authors developed the classification of gaits for a crawling robot based on several criteria: the admissible periodic separation of links from a surface, the ability to control by friction in the supports, the combinations of controllable bearing supports, and the implemented type of motion. The authors studied in detail the controllable planar gaits of a robot when moving it forward and distinguished four types of gaits: longitudinal, transverse, transverse s -shaped, and longitudinal-transverse. For each gait the sequence of stages is developed, the conditions of their beginning and end imposed on the movements of the links are formulated and the vector of generalized coordinates is defined. As a result of numerical simulation, the authors built the graphs of trajectories of the centers of mass of links and the center of mass of the entire device for each gait, as well as the graphs of time dependences of the angles of rotation of links. The study identified the influence of angles of links relative positions on the distance traveled by the robot. It is revealed that for the same time of movement, the robot will pass the greatest distance with a longitudinal gait irrespective of angles of links relative position. The device will be able to march the same distance at two types of transverse gaits at the maximum possible angle of the links relative position.
Frontier Materials & Technologies. 2019;(4):19-28
pages 19-28 views

THE INTERRELATION OF THE SIZES AND PHASE COMPOSITION OF ZR-BASED BULK AMORPHOUS ALLOYS

Drozdenko A.A., Matveev D.V., Pershina E.A., Aronin A.S.

Abstract

Bulk amorphous Zr-based alloys are promising for their high mechanical properties and thermal stability. The predominate component of Zr in the alloy significantly improves its strength, ductility, corrosion resistance and melting point, which is important when creating various structural materials. The obtainment bulk of Zr-based alloys with an amorphous structure is not a trivial goal, but requires an ad hoc approach as the high degree of Zr oxidation and the necessary high rates of melt cooling limit realization of the amorphous state. At an insufficient cooling rate during quenching, the crystalline phases are formed, which causes change in the properties of the material itself, which in turn affects the field of practical application. Therefore, it is very important to have an idea about the change in a structure during manufacture since many properties of materials are structurally dependent.During the work, the amorphous, partially crystalline and crystalline samples of the amorphized alloy of Zr55Cu30Al10Ni5 composition were obtained by levitation melting and quenching into copper moulds of variable diameter. The crystalline phases formed during quenching depending on the sizes of the sample and position in it were identified. Small differences between the values of interplanar spacing of the formed phases and the tabulated ones, which can be associated with partial substitution of atoms that leads to anisotropic lattice distortions were revealed and explained. In addition, during the work, differences in the phase composition after quenching and under decomposition of the amorphous phase during heating of the alloy of this composition were also revealed.
Frontier Materials & Technologies. 2019;(4):29-34
pages 29-34 views

SOME PRACTICAL CONCERNS RELATED TO COMPUTER PROCEDURES OF PROCESSING IMAGES IN MATERIAL SCIENCE

Kudrya A.V., Sokolovskaya E.A., Perezhogin V.Y., Ha N.N.

Abstract

The traditional approach to ranking structures and fractures as the comparison with standards (pictures) does not allow to objectively describe the existing diversity of their geometry, to provide the direct comparison of the morphology of structures and fractures to identify critical parameters of structures determining the difference in their resistance to fracture. Formalization of approaches to the description of digital images of structures and fractures is complicated, in particular, due to the differences in the mechanisms of destruction of nominally similar structures that differ in the geometry of the structure of its individual elements and their configuration as a whole; the resulting differences in the metrological support of image processing procedures. It is usually understood that this is provided by default within the framework of the specialized software products used, but in practice, the necessary attention to comparing the alternative options for image processing procedures to choose the optimal one is not always paid. In this regard, the paper considers some aspects of obtaining digital images of structures and fractures, their processing, providing reproducible and comparable results that carry meaningful information about their morphology. In particular, the authors evaluated the role of the etching duration, the choice of the optimal magnification of the microscope (in the range of values comparable in their capabilities to solve a specific problem), and the noise removal procedure. The paper discusses the approaches to the selection of effective image processing algorithms, for example, when changing over from the point estimates of structures to the measuring of their geometry (taking into account the ideas about the statistical nature of structures and fractures, measurement scales). The authors estimated the efficiency of using classical and nonparametric statistics when comparing the results of measurements of the structures and fractures geometry, and the possibility of classifying “blurry” images of microstructures based on the Fourier transform. Based on the results obtained, the authors reviewed some procedures for processing the images of structures and fractures and showed that the use of statistical characteristics of images of structures and fractures makes it possible to rank more objectively the structures according to their geometry.
Frontier Materials & Technologies. 2019;(4):35-44
pages 35-44 views

THE ELASTOPLASTIC PROPERTIES OF THE TRABECULAR BONE TISSUE

Panfilov G.P., Gilev M.V., Izmodenova M.Y., Zaytsev D.V.

Abstract

The trabecular bone tissue is a natural composite material with the developed hierarchical structure. The detailed study of its mechanical properties is important both for understanding the mechanism of injury production and for developing the optimal designs for osteosynthesis, prosthetics, and replacement of bone defects. The study of mechanical behavior of the trabecular bone under the cyclic loading is fundamental for the formation of current approaches to the prevention, as well as to the conservative and surgical treatment of fractures, as the bone tissue has different strength in different parts of the skeleton. The authors studied the uniaxial compression deformation behavior using five cylindrical specimens made from fragments of the trabecular bone tissue of lateral condyle of the tibia. The ratios of elastic and nonreversible deformations in the trabecular bone tissue of the subchondral area of the tibia under the uniaxial compression were investigated depending on the magnitude of the applied load and the total deformation. The authors carried out phased loading with the step of 0.5 % to 10 % of deformation and then with the step of 1 % to 15 % of deformation. The study showed that the trabecular bone is deformable both elastically and plastically. The elastic properties of bone tissue slightly decrease only with the appearance of macroscopic cracks in the sample. Thanks to the high porosity (30-90 %) and organic components, the trabecular bone is significantly deformable. The deformation of less than ~3 % is elastic and, therefore, does not lead to nonreversible changes in the trabecular bone tissue. With deformations exceeding 3 %, the nonreversible changes in the microstructure causing a depressed fracture of the limb bones take place in the bone tissue.
Frontier Materials & Technologies. 2019;(4):45-51
pages 45-51 views

CONCERNING THE MELTING OF AN ALUMINIUM ELECTRODE BY THE ARGON ARC OF STRAIGT POLARITY

Sidorov V.P., Sovetkin D.E., Borisov N.A.

Abstract

This paper gives the information analysis on the ratio of the melting rate of electrode wire on welding arcs of direct and reverse polarity in СО2. At equal currents, the melting rate on direct polarity arc is about two times higher than the melting rate on reverse polarity arc. When welding in shielding gases, the reason to refuse the use of direct polarity arc is the low melting rate stability of the electrode wire. It is caused by the intense moving of arc cathode spot affected by the emissivity change of the electrode surface. Within the scope of this paper, the authors propose a calculation method for arc power transmitted to a consumable aluminum electrode on various polarities. The calculated specific power (per 1 А of the current) is significantly higher for electrode-cathode, and when step-up the current, the power increases more intensively than for anode. The experiment determined the melting rate of aluminum electrode wire of 1.2 mm diameter for direct polarity arc in argon. It is as well about two times higher than for reverse polarity. Within the limits of 80-180 А currents on the arc direct polarity, there was not defined any significant dependence between the melting ratio of aluminum wire and arc current. The calculation method ensures good convergence of designed and experimental data on the ratio of electrode melting rates on different polarities. The formulas obtained allowed evaluating the effective arc power in argon for aluminum products. Further researches are to be aimed at defining the stability conditions of the melting rate of electrode wire on direct polarity arc in shielding gases. It is especially necessary for welding of heavy thickness parts to reach more efficient filling of edge preparation.
Frontier Materials & Technologies. 2019;(4):52-57
pages 52-57 views

THE INFLUENCE OF LOW-TEMPERATURE PLASMA MODIFICATION WITH CARBON AND NITROGEN ON THE HARDENING AND SURFACE ROUGHNESS OF AUSTENITIC STAINLESS STEEL

Skorynina P.A., Makarov A.V., Menshakov A.I., Osintseva A.L., Chalina M.A.

Abstract

Low-temperature plasma carburization and low-temperature plasma nitriding are the effective methods for hardening of thermally nonhardenable austenitic chromium-nickel steels. However, the ion-plasma methods of surface modification can lead to the roughness parameter increase. Previously, the authors identified that the level of surface roughness strongly depends on the temperature of plasma treatment. The hot topic of the research is the reduction of temperature of chemical and thermal treatment to ensure the effective hardening and low surface roughness of austenitic chromium-nickel steel. In this paper, using the X-ray phase analysis, microhardness measurements at various loads and optical profilometry, the authors studied the influence of carburization and nitriding in the electron beam plasma at the temperature of T =350 °C on the phase composition, microhardness and surface roughness of 04Cr17Ni8Ti austenitic steel. It is established that carburization and nitriding in the plasma generated by low-energy electron beam provides an increase in microhardness of the surface of austenitic steel in 5-6 times (from 220 to 1100 HV and 1390 HV 0.025, respectively). The effective hardening of the surface layer of austenitic steel is associated with the formation as a result of low-temperature plasma modification of carbon-supersaturated austenite γC and chromium carbides Cr23C6 during carburization, as well as S-phase (nitrogen-supersaturated austenite γN), ε-phase (Fe2-3N) and γ¢-phase (Fe4N) during nitriding. The study identified that stainless austenitic steel after carburization is characterized by the greater depth of a hardened layer than in the case of plasma nitriding. Low-temperature (at the temperature of T =350 °C) treatment in the plasma electron beam by carburization and nitriding provides the formation of a high-quality 04Cr17Ni8Ti steel surface with low values of roughness parameter Ra (185-265 nm) and, therefore, can be considered as a finishing operation during the surface hardening of austenitic steel.
Frontier Materials & Technologies. 2019;(4):58-64
pages 58-64 views

THE OXIDATION PROCESS IN THE TEXTURED THIN TAPES OF BINARY COPPER-BASED ALLOYS

Suaridze T.R., Khlebnikova Y.V., Rodionov D.P., Egorova L.Y.

Abstract

In the present work, the authors studied the development of the oxidation process in some binary copper alloys (Cu - 40 % Ni, Cu - 30 % Ni, Cu - 1.6 % Fe, Cu - 0.4 % Cr). The authors determined the principal locations for the formation of corrosion centers on the surface of textured tape substrates of Cu-Me alloys (where Me=Ni, Cr, Fe) after annealing in an oxidizing atmosphere for 5, 30, and 250 min at the temperature of 700 °С. The study established that the oxidation of the surface of thin tapes of Cu - 0.4 % Cr and Cu - 1.6 % Fe alloys is not homogeneous, in contrast to the Cu - 40 % Ni and Cu - 30 % Ni alloys. The corrosion centers formed more intensively on the segregated particles of the alloying element - pure chromium or iron with a bcc lattice. The study discovered that the oxide film formed as a result of prolonged annealing, in Cu-Cr and Cu-Fe alloys, has a greater thickness in the zone of grain boundaries. According to the X-ray spectrum analysis, in the spectra taken from the boundaries, the higher oxygen content is registered than in the central zone of a grain. The study shows that in the textured tapes of Cu-Cr and Cu-Fe alloys, both the surface oxidation and internal oxidation of tapes occur in the process of short-term annealing (700 °С, 5 and 30 min). As a result of electron-diffraction analysis, the authors identified that, in the course of oxidation, a layer of complex spinel-type CuMe2O4 (Me=Cr, Fe) oxide appears on the alloying element particles during the annealing, and the dispersed copper oxides, mainly Cu2O with a small quantity of CuO, are produced in the copper matrix.
Frontier Materials & Technologies. 2019;(4):65-72
pages 65-72 views

DIFFERENCES IN THE LOCAL ATOMIC STRUCTURE OF THE AMORPHOUS TI2NICU ALLOYS PRODUCED BY MELT QUENCHING AND LARGE PLASTIC DEFORMATIONS

Sundeev R.V., Shalimova A.V., Glezer A.M., Veligzhanin A.A.

Abstract

At present, systematic studies of structural regularities inherent in metallic materials in the process of large plastic deformations are actively proceeding. In particular, by high-pressure torsion, the authors obtained many interesting and important results. It is known, that some alloys and intermetallic compounds during the high-pressure torsion change from a crystalline to an amorphous state. However, in the literature, there is no answer to the issue of similarity or difference in the local structure of amorphous states of the same alloy produced by various methods (after melt quenching and high-pressure torsion). In the paper, using the EXAFS spectroscopy, X-ray diffraction analysis, and transmission electron microscopy, the authors studied the local atomic structure of the amorphous Ti2NiCu alloy produced by melt quenching and high-pressure torsion. It is shown that the local atomic structure of the amorphous phases produced by melt quenching and high-pressure torsion is not identical. The amorphous structure of the Ti2NiCu alloy produced by the high-pressure torsion compresses and becomes improved under the action of significant deformation effects as the strain increases at room temperature to n =6. The authors identified that the radii of the first coordination spheres of pairs of atoms of the Cu-Ti and Ni-Ti types, as well as the corresponding coordination numbers, depend on both the method of obtaining the amorphous state and the value of high-pressure torsion. The interatomic Cu-Ti and Ni-Ti distances slightly increase after high-pressure torsion at n =4 compared to the state after melt quenching. The increase in the strain up to n =6 causes the decrease in the interatomic Cu-Ti and Ni-Ti distances as compared to the state after melt quenching.
Frontier Materials & Technologies. 2019;(4):73-79
pages 73-79 views

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