No 4 (2020)

Full Issue

THE MORPHOLOGY AND MICROHARDNESS OF THE SURFACE OF AK5M2 ALLOY IRRADIATED BY AN ELECTRON BEAM

Zagulyaev D.V., Abaturova A.A., Aksenova K.V., Leonov A.A., Yakupov D.F.

Abstract

The study objective was to analyze the change in the morphology and microhardness of the AK5M2 alloy irradiated by an electron beam in various regimes. The authors modified the Al-5wt%Si alloy surface by an electron beam in the modes differed in the electron beam energy density (10, 20, 30, 40, and 50 J/cm2) and pulse durations (50 and 200 μs). The study identified that at electron beam parameters of 30 J/cm2, 200 μs, and 50 J/cm2, 50 μs, the maximum increase in microhardness to 860 MPa and 950 MPa was observed for each of the regimes, respectively. The microhardness value of the cast alloy was 520 MPa. Numerous micropores and microcracks characterize the irradiation surface morphology at beam parameters of 30 J/cm2, 200 μs. The material shrinkage during its high-speed crystallization can cause the formation of micropores. It is possible to assume that the generation of tensile stresses in a surface layer resulted from high cooling rates of a surface layer of the material from the molten state causes the formation of microcracks. The irradiation mode of 50 J/cm2, 50 μs leads to the complete dissolution of intermetallic and silicon particles in a surface layer; the crack density per surface area unit of the sample decreases against the regime of 30 J/cm2, 200 μs. The surface layer is characterized by the structure of high-speed cellular crystallization with the sizes of 500 to 800 nm formed in the volume of the grains that may cause an increase in the strength properties of the material.
Frontier Materials & Technologies. 2020;(4):7-14
pages 7-14 views

IMPROVING MATHEMATICAL, METHODOLOGICAL, AND ALGORITHMIC SUPPORT OF IMPLEMENTATION OF AN ENLARGED BLOCK OF DESIGN PROCEDURES FOR THE ANALYSIS OF REQUIREMENTS TO THE HIGHLY PRECISE PRODUCTS ASSEMBLY

Nazaryev A.V., Bochkarev P.Y.

Abstract

In current conditions, the necessity to produce many high-precision tooling and machines has increased many times over. That is why the improvement of such products manufacture becomes of paramount importance due to the increasing requirements imposed on them. The existing approaches to ensuring the quality and accuracy of high-precision products are not universal and not always can be implemented when producing high-precision goods. For a comprehensive solution to this problem, the authors proposed using an integrated approach - the complex of formalized design procedures of the system for accounting of the requirements to the high-precision products assembly when designing the manufacturing methods of machining. However, for the establishment of relations between the process design and designing preproduction of multi-product manufacture, the transition to the assessment of the production manufacturability of goods and deeper integration of this system into the structure of the system of automated sequencing of manufacturing methods, it is necessary to search for ways to improve the existing approaches of the developed system. The paper considered in detail the enlarged block of design procedures for the analysis of requirements to the assembly of high-precision products, since this stage is directly related to the designing preproduction, and the initial data obtained in the course of its implementation ensure the quality of choice of rational manufacturing methods of machining of parts. The authors propose the techniques to improve mathematical, methodological, and algorithmic support of this enlarged block implementation. The introduction of the proposed solutions will allow performing effectively the design dimensional analysis of a high-precision assembly unit in an automated mode and forming a set of assembly requirements, which, as a result, will allow ensuring the expansion of digitalization of the process design and designing preproduction and the transition to intelligent production systems.
Frontier Materials & Technologies. 2020;(4):15-24
pages 15-24 views

CHANGING THE STRUCTURE AND PROPERTIES OF HOT-DIP ZINC COATINGS USING DIFFUSION ANNEALING

Rodina A.A., Dobychina K.E., Bondareva O.S.

Abstract

Zinc coatings are widely used to protect steel goods from corrosion. The physics of methods of zinc applying to steel determines the coating morphology. Hot-dip zinc and thermodiffusion coatings are produced on steel by a diffusion mechanism and contain intermetallic phases according to the Fe-Zn diagram; however, they have different phase morphology, corrosion resistance, and consequently, different operating corrosive media. Thermodiffusion coatings have the highest corrosion resistance. However, their applying technique imposes a restraint on the dimensions of goods due to the small size of a chamber, and it requires much more time (several hours) compared to hot-dip zinc coatings applying for several minutes. In this respect, the authors suggest using the diffusion annealing of hot-dip galvanized goods to produce the entire intermetallic structure of the coating. The goal of the paper was to study the influence of the diffusion annealing modes on the microstructure and properties of hot-dip zinc coatings. The study showed the changes in the microstructure and elemental composition of the zinc coating phases as the result of soaking at the temperatures of 500 and 600 °С for 5 and 10 minutes. The authors researched the influence of annealing modes on the porosity of a coating and its microhardness. The coatings were quickly tested for corrosion resistance in the initial state and after thermal treatment. As a result of diffusion annealing, zinc coating becomes completely intermetallic, more homogeneous; its chemical composition becomes uniform. The study identified that to obtain the balance of physical-mechanical and technological properties, it is recommended to use the diffusion annealing mode with a temperature of 500 °С and soaking in a furnace for 5 minutes.
Frontier Materials & Technologies. 2020;(4):25-33
pages 25-33 views

EFFECTIVE POWER OF THE REVERSE POLARITY WELDING ARC WHEN SURFACING ALUMINUM WITH A CONSUMABLE ELECTRODE

Sidorov V.P., Kovtunov A.I., Bochkarev A.G., Sovetkin D.E.

Abstract

The paper analyzes the information about the effective power of a reverse polarity arc on an aluminum part and the influence of the arc cathode region on it. The study differentiated the effective power of the direct polarity arc into its main components. The authors carried out the experiments to measure the effective power of the reverse polarity arc for aluminum welding. To determine the effective power, the calorimetry was used when hardfacing a wire of 1.2 mm diameter on the Al-Mn alloy plate and the deposited metal then was weighed. Based on the experiment results, the authors calculated an average algebraic deviation of αН∙I hardfacing performance and effective power. As a result, the authors proposed the procedure to determine the electrode wire fusion coefficient at zero stick-out α0 according to its dependence on the arc current, which increases at electrode diameter decreasing. This coefficient is about 25 % less than that of steel. By assuming a weak dependence of anode power on the arc current, this fact proves the obtained data on the high heat content of electrode metal droplets of an aluminum wire in comparison with a steel wire. At the droplet transfer of electrode metal, the cathode region power of the arc makes the prevailing contribution to the total effective power of the reverse polarity arc. At the current density equal to 175 А/mm2, the specific effective power of the cathode region action is qSC=9.0 W/А, the power of the electrode metal is qE=4.6 W/А, and the plasma flow power is qP=5.2 W/А.
Frontier Materials & Technologies. 2020;(4):34-42
pages 34-42 views

THE STUDY OF THE INFLUENCE OF ZNCL2 CONTENT IN A FLUX FOR BRAZING OF AL-MG ALLOYS ON ITS TECHNOLOGICAL PROPERTIES

Stepanov M.A.

Abstract

Aluminum-magnesium alloys are ductile alloys with good weldability, corrosion resistance, and a high fatigue strength level. Aluminum-magnesium alloys contain up to 6 % magnesium. The higher its content, the stronger is the alloy. However, these alloys with high magnesium content are difficult to solder. Therefore, the task is to create flux compositions for high-temperature brazing of these alloys providing high-quality brazed joints. The work investigated the influence of the ZnCl2 activator on the technological properties of the flux. The authors tested the flux compositions with ZnCl2 content of 0 to 12 %. The tests were carried out on the AMg2 alloy using the AK12 solder. The authors evaluated the influence of ZnCl2 content on the spreading area of solder, the spreading uniformity, and the surface condition. The study revealed a significant increase in the spreading area of solder when introducing the ZnCl2 activator into the flux and the introduction of 4 % zinc chloride made it possible to increase the spreading zone of a solder drop by 50-55 %. The authors considered the samples brazed with a flux that did not contain ZnCl2 and using flux with the addition of 4 % ZnCl2. Activator content in the flux increased by 4 % before reaching 12 %. The study identified the strong interaction between the flux and the base metal with the release of gaseous products leading to the pore formation. As a result of the work, it was revealed that ZnCl2 significantly affects the flux properties, allowing increasing the solder spreading area; however, in the result of reactions with the formation of gaseous products, it can lead to the porosity of the brazed joint.
Frontier Materials & Technologies. 2020;(4):43-50
pages 43-50 views

THE TECHNOLOGIES OF IMPROVING THE PROCESS OF AIR-FUEL MIXTURE COMBUSTION IN SPARK IGNITION ENGINES

Shaikin A.P., Galiev I.R., Pavlov D.A., Sazonov M.V.

Abstract

The paper considers the turbulence intensity and the fuel chemical composition impact on the flame propagation velocity at the initial and main combustion phases when changing the air-fuel mixture composition. The relevance of the study is caused by the fact that currently, the improvement of conventional engine operation characteristics is mainly achieved through the improvement of the fuel mixture combustion process. However, there are no data on the influence of chemical and gas-dynamic factors on the peculiarities of flame propagation at the initial and main combustion phases. The gas reciprocating internal combustion engine was the object of the research, and the subject of the study was the fuel combustion process. Fuel chemical composition changed due to the promoting addition of hydrogen to the natural gas and variations of the excess-air coefficient. The experiments carried out on the UIT-85 power plant (i.e. under the simulated internal combustion engine conditions) show that the promoting addition of hydrogen stronger influences the flame velocity in the initial combustion phase compared to the second combustion phase, as a combustion source in the first phase is a laminar flame bent front and depends only on chemical and thermo-physical properties of the fuel-air mixture. The analysis of experimental data showed the dual impact of turbulence intensity on the flame propagation velocity. In particular, at the beginning of the combustion process, the fluctuating velocity scarcely influences the flame propagation velocity, as opposed to the main combustion phase, where the flame propagation velocity increases at the increase of turbulence intensity.
Frontier Materials & Technologies. 2020;(4):51-57
pages 51-57 views

THE RESEARCH OF INTERACTION OF ZINC SOLDERS WITH ALUMINUM ALLOYS DURING FRICTION APPLICATION

Shargaev E.O., Pashkov I.N.

Abstract

Nowadays, due to the search for more efficient and steady processes of aluminum combination and the products that cannot be manufactured using flux, the issue of application of flux-free soldering methods for aluminum-based alloys is highly relevant. The lack of the description of the processes and mechanisms of flux-free soldering by the technique of friction of the solder on the aluminum surface makes it urgent to study and describe them in detail. To carry out the study, the authors produced zinc-based alloys and prepared solder rods using the hot pressing method. Using the technique of friction of a rod against the surface of the heated aluminum substrate, the authors identified minimum temperatures of the setting of zinc solders of different compositions with aluminum surfaces. The experiment proves that these temperatures correlate with the liquidus temperatures of these alloys and have similar values. The dependence of minimum setting temperatures on the Al and Cu content in the solder was obtained. The authors studied the influence of the state of the base metal surface on the spreading area of the Zn-4%Al zinc solder during friction application. The experiments determined the zones of solder spreading over the surface of the AD31 aluminum alloy substrate, depending on the roughness of the base metal surface. The study identified that minimum setting temperatures of solders have similar values against the liquidus temperatures of these alloys, and the adding of copper to a solder reduces these temperatures, on average, by 20° С per each percent of added copper. The flowing of Zn-4%Al solder over the AD31 aluminum alloy surface reaches the largest values when treating the surface with rough-grain abrasive cloths, and the flowing effect decreases with the decrease in roughness.
Frontier Materials & Technologies. 2020;(4):58-66
pages 58-66 views

THE RELATIONSHIP BETWEEN THE ANOMALIES OF THE PROPERTIES OF ALLOYS WITH A SEMICONDUCTOR COMPONENT AND SPECIAL FEATURES OF GLASS FORMATION AND STATE DIAGRAMS

Shakhnazarov K.Y., Mikhailov A.V., Tzykanov D.V.

Abstract

The analysis of literature data on the properties of alloys with a semiconductor component shows a significant number of anomalies of physical and mechanical properties left without a comment of the researchers of these alloys. Based on the anomalies in the properties of twelve alloys (Ge-Si, InAs-GaP, GaSb-GaAs, HgTe-CdTe, GaSe-GaS, InSb-AlSb, PbSe-GeTe, Zn-Ge, Ti-Ge, Ge-Tl, ZnTe-HgTe, P-As), the paper attempts to identify a regularity that allows associating these anomalies with state diagrams. For the first time, the authors introduce the concept of phase diagram as a concentration dependence of qualitative changes in crystallization intervals, which allows associating phase diagram with the extremes of physical and mechanical properties of industrially used alloys with a semiconductor component that cannot be explained by the peculiarities of phase composition or structure. The second part of the paper deals with the special aspects of glass formation (amorphization) of multicomponent alloys. Modern literature expresses mutually exclusive judgments about the possibility of using phase equilibrium diagrams to predict the ability to glass-formation, which is well-founded and is probably associated with the absence of a general theory of glass formation. Nevertheless, the analysis of literature data on SiO2-Na2O, Ge-S, GeSe-Se, S-Se alloys shows that the glass formation (amorphization) boundaries are associated with phase diagrams. Based on the identified criterion, the paper shows the possibility of using equilibrium state diagrams built for slow-cooled alloys to predict the glass-forming ability of (fast-cooled) alloys.
Frontier Materials & Technologies. 2020;(4):67-77
pages 67-77 views

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