No 2 (2022)

Cover Page

Full Issue

Investigation of damages formed in polymer composite materials under bending loading and their identification by the acoustic emission technique

Bryansky A.A., Bashkov O.V., Belova I.V., Bashkova T.I.

Abstract

Polymer composite materials (PCM) reinforced with glass fibers are very important in many industries due to their unique properties (high chemical resistance and specific strength) with the economic efficiency of use. At the same time, the application of glass fabrics as reinforcing elements ensures high manufacturability. However, unlike crystalline materials, polymer composite materials are subject to the complex process of destruction, which requires the application of non-destructive control methods to get information about the nature of the resulting damage and the kinetics of their accumulation. The paper studies the deteriorations formed in the fiberglass samples molded using T-11-GVS-9 glass fabric and DION 9300 FR binder within static bending deformation accompanied by the acoustic emission (AE) method. In this work, the authors solved the problem of identifying the nature of damages in fiberglass using the Fourier spectra of the recorded AE signals. The authors used the clustering method to estimate their formation and development kinetics. Clustering was performed based on the Kohonen self-organizing map (SOM) algorithm using the values of peak frequencies of the Fourier spectra calculated for the recorded AE signals under static bending deformation of a fiberglass sample up to failure. To ensure the separability of the resulting damages according to the AE parameters, the authors used the loading rate that was ten times lower than that calculated according to the state standard. The study established that the application of frequency representation of AE signals recorded during the fiberglass destruction is effective when solving the task of identifying the nature of the resulting damages. As a result of the study, the authors found that the process of delamination formation during the bending of multilayer laminated plastics acts as a critical mechanism of destruction leading to a significant loss of the polymer composite strength properties.

Frontier Materials & Technologies. 2022;(2):7-16
pages 7-16 views

Optimizing the layout of a CNC lathe

Denisenko A.F., Grishin R.G.

Abstract

A reasonable choice of machine layout is one of the ways to improve the quality of CNC machines and the result of a comprehensive analysis and consideration of many frequently conflicting requirements: accuracy, design feasibility, processability, productiveness, efficiency, safety, etc. The complexity of the choice of machine layout is associated with their diversity depending on the fact that machines with different designs of assembly units can have the same arrangement and, conversely, lathes with the same designs of main elements can have different layouts. Due to the multiple effects of layout on the accuracy characteristics of a machine, the optimal layout solution choice is the priority problem of machine building. The study covers the development of a technique for selecting a layout solution for the CNC lathes, which considers the random location of cutting zones and the existence of power factors related to the design and layout of a spindle unit. In the developed technique, as a criterion for choosing an optimal arrangement, the authors suggest using an accuracy layout criterion evaluated by the elastic deformations of a spindle in the cutting zone. The study resulted in analytical expressions for an objective function depending on two design variables: angles determining the location of a spindle pre-drive gear and a tool-holding group. The authors note that for the precision lathes when identifying spindle bearing radial stiffness, one should take into account the stiffness anisotropy of a housing bore for the spindle front support. For two specified design variables, the study shows the performance of a scanning method (complete enumeration for 322 points). Using this method and processing with Mathcad software, the authors obtained a possible variation range of values of specified angles for five standard layouts of spindle support bearings and limitations related to the minimization of elastic deformations of the tooling system.

Frontier Materials & Technologies. 2022;(2):17-27
pages 17-27 views

Influence of dislocation and twin structures on the mechanical characteristics of Ni–Mn–Ga alloys at ultrasonic frequencies

Kaminskii V.V., Kalganov D.A., Podlesnov E., Romanov A.E.

Abstract

Magnetic shape memory alloys are a specific subtype of shape memory materials. The magnetic deformation phenomenon causes the high research interest in these alloys. Thus, in one of the most promising alloys based on Ni–Mn–Ga, using a magnetic field, it is possible to achieve changes in a single crystal size by up to 10 % due to the reorientation of the magnetic field in magnetic domains. The high magnetic deformation is directly related to the high mobility of twin boundaries separating two domains. In this work, the authors used a composite piezoelectric oscillator at a frequency of about 100 kHz to determine the influence of such defects as dislocations and twin boundaries on the mechanical characteristics of Ni49Mn30Ga21. The authors investigated the features of temperature dependences of internal friction in the samples before and after deformation and provided the amplitude dependences of these characteristics. In the studied single-crystal martensitic phase, the transition from the tetragonal phase to the orthorhombic phase was detected at 235 K. In the Ni–Mn–Ga tetragonal phase, the formation of new defects contributes to the more pronounced and early onset of amplitude-dependent internal friction. At lower loads, the successive stages occur associated with the processes of dislocations and twin boundaries movements inside the Cottrell clouds, dislocations and twin boundaries movement outside the Cottrell clouds, and supposedly, the slowdown of dislocations and twin boundaries movement due to their interaction. As well as internal friction, the authors studied the change in Young’s modulus. Its decrease at all temperatures is most pronounced in the samples with the defective structures. The study identified that in the orthorhombic phase, it is possible to observe the internal friction dependence on the deformation amplitude at a lower load due to an increase in the twin boundaries mobility with increasing temperature.

Frontier Materials & Technologies. 2022;(2):28-36
pages 28-36 views

Nucleation and growth of fullerenes and nanotubes having three-fold T-symmetry

Melker A.I., Krupina M.A., Matvienko A.N.

Abstract

According to the periodic system of fullerenes, all the fullerenes can be classified into the groups having different symmetry. It is supposed that the fullerenes of one and the same symmetry have similar properties. Before the appearance of the periodic system in 2017 the fullerenes were chosen for study at a random way that instead of ordering the results only increased information entropy. We have studied possible ways of generation and growing the fullerenes, which refer to the group having three-fold T-symmetry. Beginning with cyclopropane C3H6 producing clusters C6, we have obtained elementary fullerenes C6 as well as mini-fullerenes C12, which in their turn have produced the fullerenes from C18 to C48, perfect and imperfect, as well as nanotubes. The basic perfect fullerenes C18, C24, C30, C36, C42 and C48 have the ordinary three-fold symmetry, the intermediate ones having no such symmetry. Their imperfection is connected with extra ‘interstitial’ or carbon dimers, the dimers playing the role of defects. One can define the imperfect fullerenes with defects as the fullerenes having topological three-fold symmetry. We have calculated their shape and energies using Avogadro package and discussed possible reasons of their dependence on a fullerene size and shape. We have found that the fullerenes can be divided into two groups, alive that can grow, and dead which are impotent. Taking into account the results obtained early, allows us to make predictions that the dead fullerenes C24R, C32R, C40R and C48R of three-, four-, five- and six-fold symmetry have the most chance to be found experimentally with comparison of their isomers.

Frontier Materials & Technologies. 2022;(2):37-53
pages 37-53 views

Metallographic examination as the feedback between product quality and manufacturing

Merson D.L., Karavanova A.A., Klimanov A.V.

Abstract

Despite the increasing automation of the process of designing and manufacturing metal products, their failure remains a common phenomenon. The metallographic examination is appointed, which can only be carried out at a proper level by the specialized accredited organizations to identify the causes of such incidents. A metallographic examination is a tool that acts as feedback between the output quality of products and the entire chain of numerous operations during production. The purpose of this work is, using a practical example, to demonstrate the possibility and special significance of the conclusions of the metallographic examination for the development of the product manufacturing technology. Using the high-speed plasma spraying method, the authors applied the NiCrBSi coating to the surface of the locomotive wheel pair axle to increase its wear resistance. The life bench tests of the axle revealed the main fatigue crack, the tests were stopped, and the axle was artificially broken completely. The analysis of metal quality, including chemical composition, mechanical properties (strength, ductility, and impact hardness), microstructure, metal purity according to the non-metallic inclusions, and parameters of a surface layer hardened by rolling, showed its full compliance with the regulatory documentation. The thickness and hardness parameters of the NiCrBSi coating also corresponded to the declared ones. According to the fractographic analysis, the fatigue fracture was initiated at multiple points, which was a characteristic sign of a common objective reason for the insufficient strength of a product not associated with some random factor. The metallographic examination identified that the main reason for the failure of a wheelset axle is the coating’s insufficient fatigue strength. The numerous fatigue microcracks that originated in the coating grew into the base metal and led to the fatigue macrocracks formation at different height levels. The merging of these cracks led to widespread fatigue fracture surface formation.

Frontier Materials & Technologies. 2022;(2):54-62
pages 54-62 views

Structure effect on the kinetics and staging of the corrosion process of biodegradable ZX10 and WZ31 magnesium alloys

Myagkikh P.N., Merson E.D., Poluyanov V.A., Merson D.L.

Abstract

Biodegradable magnesium alloys are one of the most promising materials for osteosynthesis surgical implants due to the combination of unique properties: high strength, low weight, Young’s modulus close to the bone’s one, and low cytotoxicity. The most important performance characteristic is the corrosion rate, which determines the lifetime of an implant. At the moment, the main efforts of the researchers are aimed at finding a material with optimal corrosion properties ensuring the preservation of the operational properties of an implant during the bone healing period. Most of the works on this issue cover the study of the influence of the alloy chemical composition. At the same time, it is widely known that the structure of a material can also have a great effect on corrosion, for example, grain refinement can even change its type. Besides, it is important that the materials with the same quantitative parameters of corrosion can be substantially different in terms of the corrosion process staging. The authors studied the WZ31 and ZX10 magnesium alloys in two states: as-cast (coarse-grained) and after multi-axial isothermal forging and pressing (fine-grained), using the up-to-date in-situ methods that allow monitoring the dynamics of changes in the corrosion rate, as well as the staging of the corrosion damage development on the sample surface. Such methods are the corrosion rate measuring by hydrogen evolution and the sample’s surface video-monitoring during the corrosion attack. The authors carried out tests within the conditions similar to the human body conditions, such as temperature, the corrosion environment composition, and pH level. The obtained results show that the type of corrosion of the WZ31 alloy changes with the decrease in the grain size from a relatively uniform to a highly localized corrosion. In contrast, the ZX10 alloy showed a decrease in the corrosion rate with the decreasing grain size, but the corrosion type did not change.

Frontier Materials & Technologies. 2022;(2):63-73
pages 63-73 views

Identification of deformations of cylindrical specimens by optical method using the technique of digital image correlation

Rastorguev D.A., Semenov K.O.

Abstract

A provision of location tolerances and their retention in the postoperative period is one of the main hard-hitting process tasks when producing long-length low-rigidity shaft-type parts. Mixed treatment – tensile straightening or thermal-power treatment is one of the technological methods intended to provide this group of geometrical indicators, including axle linearity. The efficiency improvement of this technology is impossible without knowing the features of the formation of plastic deformations distribution along the length of long-length blank parts. The paper considers the application of an optical method for controlling deformation on the surface using the method of digital image correlation at axial deformation of cylindrical parts. The work describes an experimental device for optic control of deformations when loading a specimen using digital cameras. The authors studied the influence of various modes of paint deposition to a sample (deposition rate, distance, deposition mode – continuous or pulsed) on the features of a produced speckle in the form of random distribution of mixed-size paint spots over the specimen surface; obtained histograms of the intensity distribution of various speckles. The authors carried out the experiments to identify deformations based on the technology of the local gradient digital image correlation method for the specimens of polymer tubes with different speckle types. The study identified the distribution of the deformation over the length of samples within the deformable area selected for analysis with the specified degree of smoothing provided by choice of correlation kernel size and the choice of its displacement step for fixing deformation processes with a precise error. The authors obtained distributions of axial deformations along the length of specimens and errors of deformations determination depending on a speckle nature. The study specifies necessary speckle parameters ensuring minimal error for long-length samples up to 200 mm in length and appropriate technology for paint depositing. It is a speckle with a wide range of spot sizes rarefied with their locations and the Gaussian filter image smoothing before the analysis.

Frontier Materials & Technologies. 2022;(2):74-83
pages 74-83 views

The technique for calculating the strength of a globoid worm gear

Suslin A.V., Barmanov I.S.

Abstract

Worm gears are widely used in mechanical engineering. Recently, worm gears with a globoid worm attract a considerable interest. To improve the quality characteristics of globoid gears, their geometric dimensions and parameters, as well as the production technologies are being improved. It is also important to have a methodology for calculating the strength, which is, however, currently unavailable, and the state standards cover the issue of determining and calculating only the transmission geometry. In this regard, the development of the technique for calculating the contact and bending strength of a globoid worm gear appears relevant. The basic areas of the research are gear enhancement, production technology improvement, the gearing pattern study, working surfaces mathematical simulation, 3-D modeling, and the transmission calculation. The contact strength calculation is based on the Hertz’s formula taking into account the geometric features of globoid worm gears. The authors developed the calculation of the bending strength of the worm gear teeth based on the helical gear calculation method. The paper presents data on the influence of the mechanical properties of the materials of a worm and a worm gear wheel on the gear contact strength, gives the computed coefficients estimated values. The authors note that the dynamic load factor can increase significantly with the wear of the gear working surfaces. The research findings can be used to develop the design calculation technique, as well as to improve it to take into account the effect of transmission wear and working temperature on the operation duration.

Frontier Materials & Technologies. 2022;(2):84-91
pages 84-91 views

Additive manufacturing of parts with three-dimensional continuous fiber reinforcement

Torubarov I.S., Drobotov A.V., Gushchin I.A., Vdovin D.S., Plotnikov A.L., Yakovlev A.A.

Abstract

One of the key challenges in additive manufacturing of plastic goods using the Fused Filament Fabrication (FFF) technology is to ensure their strength. The low strength of polymer materials and the distinct anisotropy of their mechanical properties limit the use of 3D printing as an alternative to the traditional small-scale production technologies. The most promising solution to the goal of increasing the strength of printed goods is the application of continuous fiber reinforcement. Several additive manufacturing devices and software products that allow preparing a control program for 3D printing with reinforcement are known, however, having all their advantages, they, like conventional printed products, have a wide spread in strength in various directions (in the plane of a layer and perpendicularly to it, in the direction of growing). In this paper, the authors propose using the continuous fiber reinforcement along the three-dimensional trajectories to smooth out the anisotropy of the products’ properties in the FFF technology and ensure wider possibilities for using them in the production of final goods. In the course of work, a 3D printer with the ability to print using five degrees of freedom and software for preparation of control programs were upgraded for the printing process with laying continuous fiber; printing modes with reinforcement were developed; samples were produced for standard static bending tests. The experiments show that reinforcement improves the printed specimen’s strength, and the proposed three-dimensional reinforcement technique ensures the lower flexing strength compared to standard flat reinforcement with uniaxial laying of fibers, though, the destruction of 3D reinforced specimens occurred without evident delamination.

Frontier Materials & Technologies. 2022;(2):92-104
pages 92-104 views

The structure and mechanical properties of biomedical magnesium alloy Mg–1%Zn–0.2%Ca

Khudododova G.D., Kulyasova O.B., Nafikov R.K., Islamgaliev R.K.

Abstract

It is known, that magnesium-based alloys are the appropriate materials to be used as biodegradable metals to produce new-generation medical implants. Magnesium can decompose in the human body during the healing process. If dissolution is controlled, there is no need in additional operation for implant removal after healing completion. Particularly, Mg-Zn-Ca alloys are considered the most appropriate biodegradable metal implants due to their biocompatibility. In the Mg-Zn-Ca alloys, the addition of Zn and Ca as alloying elements can improve the mechanical properties and increase the corrosion resistance compared to pure Mg without affecting biocompatibility. The work covers the study of the structure and mechanical properties of the magnesium Mg-1%Zn-0.2%Ca alloy after severe plastic deformation (SPD). The research of the structure was carried out using scanning and transmission electron microscopy. The study of mechanical properties was carried out by measuring microhardness and tension tests. The study shows that applying the equal channel angular pressing (ECAP) method and additional treatment with the severe plastic deformation (SPD) method to the Mg–1%Zn–0.2%Ca alloy leads to the formation of the ultra-fine grain (UFG) structure with the average grain size of less than 1 micron. The authors identified that, as a result of strong refinement of the magnesium alloy grain structure, the ultimate strength increases twice up to 283 MPa compared to the homogenized state, when the ultimate strength is 125 MPa. At the same time, in the UFG state, the plasticity significantly decreases up to 3 %.

Frontier Materials & Technologies. 2022;(2):105-112
pages 105-112 views

The comparative analysis of change in the structure and properties of Al–Si system alloys exposed to electroexplosive alloying

Shlyarova Y.A., Zagulyaev D.V., Gromov V.E.

Abstract

The paper presents the comparative analysis of the structure and mechanical properties (microhardness) of the surface layers of the hypoeutectic Al–11Si alloy and hypereutectic Al–20Si alloy exposed to electroexplosive alloying (treatment mode: aluminum foil mass is 58.9 mg; Y2O3 powder mass is 88.3 mg; the discharge voltage is 2.6 kV). During the research, the authors identified that the Al–11Si alloy initial structure mainly consists of the Al solid solution grains. Eutectic grains are located along the grain boundaries and at the joints of aluminum grain boundaries. In the Al–11Si alloy, the aluminum grain size varies from 25 μm to 100 μm, and the Al–Si eutectic grain size varies within 10–30 μm. The hypereutectic composition Al–20Si alloy in the initial state is characterized by the presence of primary silicon inclusions predominantly of a plate-like shape. The sizes of these inclusions reach 120 μm. After electroexplosive alloying, in the Al–11Si alloy, the author identified the formation of a multilayer structure consisting of a highly-porous coating irregular in thickness, a liquid-phase alloying layer, and a heat-affected layer. The modified layer thickness for the Al–11Si alloy varies in the range of 33–60 μm, and for the Al–20Si alloy, the modified layer thickness varies within 20–100 μm. The microhardness value of the initial hypoeutectic Al–11Si alloy was 64 HV0.05, for the hypereutectic Al–20Si alloy – 71 HV0.05. It can be noted that the microhardness of the Al–11Si alloy surface layer exceeds the initial material microhardness more than 2.5 times. In the Al–20Si alloy, the surface layer microhardness exceeds the one of the initial material more than twice. With the increase of the distance from the modification surface, the microhardness decreases and reaches the initial alloy value at the depth of ≈90 μm.

Frontier Materials & Technologies. 2022;(2):113-120
pages 113-120 views

Investigation of heat release in nanomodified elastomers during stretching and torsion under the action of electric voltage

Shchegolkov A.V., Shchegolkov A.V., Zemtsova N.V.

Abstract

The authors studied the elastomers modified with carbon nanotubes (MWCNTs) with a mass concentration from 1 to 8 % wt. and investigated the modes of heat release of nanomodified elastomers within the range between 30 and 260 V (of alternating current) at different levels of stretching and torsion. Samples of elastomers with the MWCNT concentration from 1 to 5 % wt. in the supply voltage range up to 260 V did not generate heat. The study showed that heat release when feeding composites of elastomers with MWCNTs was observed at a mass concentration of 6 % wt. of MWCNTs and a supply voltage of 70 V. The maximum voltage for an elastomer sample with 6 % wt. of MWCNTs reaches 260 V. An increase in concentration to 7 % wt. causes the increase in the heat release power and the decrease in the maximum supply voltage level to 180 V when the initial heat release voltage is 40 V. At the 8 % wt. concentration, the power increases, and the limiting voltage drops to 100 V, while the initial voltage becomes 36 V. The study identified that when twisting elastomer by 360°, the areas with an increased temperature on the right and in the central zone of the sample (49.5 °C) are formed. The temperature at the bend point increases up to 50.2° С when twisting elastomer by 540°. An increase in the twisting angle to 1080° leads to the formation of areas with the elevated temperature near the right-side current-carrying clamp. It is worth noting the possibility of using the produced samples of elastomers with MWCNTs as sensitive elements of strain sensors, which will allow obtaining the information on physical and chemical parameters according to the principles of measuring the change in electrical resistance that occurs during stretching and torsion.

Frontier Materials & Technologies. 2022;(2):121-132
pages 121-132 views

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